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Development
of
Carbon
Nanofiber
Composite
Materials
for
Supercapacitors
in
Energy
Storage
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Development of Carbon Nanofiber Composite Materials for Supercapacitors in Energy Storage

Innovation Owner

SS

Somchai Sonsupap

Advisor

Details

This study presents the development of carbon-based multiphase metal oxide nanocomposites (CNF@MOx) as electrode materials for supercapacitors, fabricated via electrospinning and annealing in an argon atmosphere.

This study presents the development of carbon-based multiphase metal oxide nanocomposites (CNF@MOx; M = Ag, Mn, Bi, Fe) incorporating silver, manganese, bismuth, and iron nanoparticles within polyacrylonitrile (PAN)-derived carbon nanofibers.

  • Fabrication: Produced via the electrospinning technique followed by annealing in an argon atmosphere.
  • Structural Properties: The nanofibers exhibit a uniform structure with diameters ranging from 559 to 830 nm and embedded nanoparticles of 9-21 nm.
  • Electrochemical Performance: CNF@Ag/Mn/Bi/Fe-20 achieved a maximum specific capacitance of 156 F g⁻¹ at a scan rate of 2 mV s⁻¹.
  • Stability: Retains over 96% of its capacitance after 1400 charge-discharge cycles.
  • Mechanism: The synergistic combination of electric double-layer capacitance and redox-based charge storage enhances performance.
Development of Carbon Nanofiber Composite Materials for Supercapacitors in Energy Storage

Objective

The project aims to synthesize and develop metal oxide-doped carbon nanofibers, analyze their physical and electrochemical properties, and evaluate their performance as supercapacitor electrodes.

  1. Synthesize and develop multiphase metal oxide-doped carbon nanofibers (CNF@MOx; M = Ag, Mn, Bi, Fe) using electrospinning and calcination in an argon atmosphere.
  2. Analyze the structure and physical properties of the synthesized materials, including particle size, porosity, and metal oxide oxidation states.
  3. Investigate the electrochemical properties of the synthesized materials to evaluate their supercapacitor charge storage capacity.
  4. Compare the performance of the synthesized electrode materials with existing materials, considering specific capacitance, charge-discharge cycle stability, and energy storage mechanisms.